バイオマスからクリーンエネルギー及び化成品の製造
メンバー： 銭衛華
分野： プロセス・化学工学、複合化学、環境保全学
所属： 工学研究院
キーワード： クリーンエネルギー製造、水素化精製、バイオ燃料、バイオマス変換
ウェブサイト：
研究概要
触媒化学及び化学工学に基づいて、環境に調和しながら、バイオマスからクリーンエネルギー及びバイオマテリアルを製造するプロセス及び触媒の開発を行っている。様々な細孔構造や表面酸・塩基特性を制御した多孔質材料は、固体酸・塩基触媒あるいは各種の遷移金属担持触媒の単体として開発されている。現在行われている研究は、（１）不可食植物油から次世代バイオ燃料の製造、（２）不可食植物油から蓄熱材（PCM)の製造、（３）固体酸・塩基触媒を用いた植物油のエステル交換反応及び改質反応、（４）固体酸を用いたセルロース系バイオマスから単糖類及びHMF等の製造、（５）合成ガスから高級アルコールの合成等である。
主要論文・参考事項
1．Effect of reduction temperature of NiMoO3-x/SAPO-11 on its catalytic activity in hydrodeoxygenation of methyl laurate, Ning Chena, Shaofeng Gongb, Eika W. Qian, Applied Catalysis B: Environmental, 174, 253–263 (2015).
2．Role of support in deoxygenation and isomerization of methyl stearate over nickel–molybdenum catalysts, Eika W. Qian, Ning Chen, Shaofeng Gong, Journal of Molecular Catalysis A: Chemical 387, 76–85 (2014).
3．Liquefaction of Lignocellulosic Biomass in Protonic Solvents, Hisakazu SHIRAI, Hirokazu ARIGA, Eika Weihua QIAN, Journal of the Japan Institute of Energy, 93 (6), 548-554 (2014).
4．Effects of Adding Cobalt and Potassium on MoS2-Based Catalysts in Mixed Alcohol Synthesis, Takashi Toyoda, and Eika W. Qian, Journal of the Japan Petroleum Institute, 57 (4), 2014, 171-182.
5．CO Hydrogenation on Group VI Metal-Ceria Catalysts, Takashi Toyoda, Yoshiro Nishihara, and Eika W. Qian, Fuel Processing Technology, 125, 86-93 (2014).
6．Mixed Alcohol Synthesis over Sulfided Molybdenum-Based Catalysts, Toyoda, Takashi; Minami, Takayuki; Qian, Eika W., ENERGY & FUELS, Volume: 27 (7), 3769-3777 (2013).
7．Single-step Hydroconversion of Jatropha Oil to High Quality Fuel Oil over Reduced Nickel-Molybdenum Catalysts, Ning Chen, Shaofeng Gong and Eika W. Qian, J. Jpn. Petro. Inst., 56(4), 249-252 (2013).
8．Effects of Si/Al Ratio and Pt Loading on Pt/SAPO-11 Catalysts in Hydroconversion of Jatropha Oil, Ning Chen, Shaofeng Gong, Hisakazu Shirai, Toshitaka Watanabe, Eika W. Qian, Applied Catalysis A, Volume 466, 105–115 (2013)
9．Hydrodenitrogenation of porphyrin on Ni-Mo based catalysts, Eika W. Qian, Satoshi Abe, Kurahashi, Tetsuya, Yusaku Kagawa, Hiroyuki Ikeda, Chinese Journal of Catalysis 34 (2013) 152–158
10．Isomerization of n-Alkanes Derived from Jatropha Oil over Bifunctional Catalysts, Shaofeng Gong, Ning Chen, Shin Nakayama, Eika W. Qian, Journal of Molecular Catalysis A: Chemical, 370, 14– 21 (2013).
11．Role of Support in Hydrotreating of Jatropha Oil over Sulfided NiMo Catalysts, Shaofeng Gong, Akira Shinozaki, Eika W. Qian, Industrial & Engineering Chemistry Research, 51(43), 13953-13960 (2012).
12．Hydrotreating of Jatropha Oil over Alumina Based Catalysts, Shaofeng Gong, Akira Shinozaki, Mingliang Shi, Eika W. Qian, Energy & Fuels, Vol.26 (4)，2394-2399 (2012).
13．Preparation of sulfo group bearing mesoporous silica-based solid acid catalysts and its application in direct saccharification, Sen Li, Eika W. Qian, Hosomi Masaaki , Tetsuya Fukunaga, Journal of Chemical Engineering of Japan, Vol. 45, No. 7, 484-492 (2012).
14．Catalytic hydrothermal saccharification of rice straw using mesoporous silica-based solid acid catalysts, Sen Li, Eika W. Qian, Tomohiro Shibata, Masaaki Hosomi, Journal of the Japan Petroleum Institute, Vol. 55, No. 4, 250-260 (2012).
15．Direct saccharification of rice straw using a solid acid catalyst, Sen Li, Eika W. Qian, J. Jpn. Inst. Ener. , Vol 90, No 11, 1065-1071 (2011).
お問い合わせ先
東京農工大学・先端産学連携研究推進センター
urac[at]ml.tuat.ac.jp（[at]を@に変換してください）
Conversion of Biomass to Clean Fuels and Chemicals
Research members： Eika Weihua Qian PhD.
Research fields： Process/Chemical engineering, Applied chemistry, Environmental conservation
Departments： Institute of Engineering
Keywords： Clean energy production, hydrotreating, biofuel, biomass transformation
Web site：
Summary
Build on Catalytic Science and Chemical Engineering, we study how to develop novel catalysts and processes to efficiently manufacture clean fuel oil and materials in an eco-friendly way from biomass. Various materials with controllable pore structures (meso, macro, and micropores), and acidic and basic properties are developed to use as a solid or base catalyst and/or a support of a catalyst. The research projects include (1) Production of second generation diesel fuel with high cetnce number from non-edible vegetabl oil by hydrodeoxygenation and selective isomerization, (2) Production of phase change material (PCM) from non-edible vegetable oil, (3) Transesterification and isomerization of non-edible vegetabl oil using solid acid catalysts, (4) Hydrolysis of cellulosic biomass to monosaccharides and HMF to produce bio-ethanol and bio-materials by using solid acid catalysts, (5) Higher alcohols synthesis from syngas.
Reference articles and patents
1．Effect of reduction temperature of NiMoO3-x/SAPO-11 on its catalytic activity in hydrodeoxygenation of methyl laurate, Ning Chena, Shaofeng Gongb, Eika W. Qian, Applied Catalysis B: Environmental, 174, 253–263 (2015).
2．Role of support in deoxygenation and isomerization of methyl stearate over nickel–molybdenum catalysts, Eika W. Qian, Ning Chen, Shaofeng Gong, Journal of Molecular Catalysis A: Chemical 387, 76–85 (2014).
3．Liquefaction of Lignocellulosic Biomass in Protonic Solvents, Hisakazu SHIRAI, Hirokazu ARIGA, Eika Weihua QIAN, Journal of the Japan Institute of Energy, 93 (6), 548-554 (2014).
4．Effects of Adding Cobalt and Potassium on MoS2-Based Catalysts in Mixed Alcohol Synthesis, Takashi Toyoda, and Eika W. Qian, Journal of the Japan Petroleum Institute, 57 (4), 2014, 171-182.
5．CO Hydrogenation on Group VI Metal-Ceria Catalysts, Takashi Toyoda, Yoshiro Nishihara, and Eika W. Qian, Fuel Processing Technology, 125, 86-93 (2014).
6．Mixed Alcohol Synthesis over Sulfided Molybdenum-Based Catalysts, Toyoda, Takashi; Minami, Takayuki; Qian, Eika W., ENERGY & FUELS, Volume: 27 (7), 3769-3777 (2013).
7．Single-step Hydroconversion of Jatropha Oil to High Quality Fuel Oil over Reduced Nickel-Molybdenum Catalysts, Ning Chen, Shaofeng Gong and Eika W. Qian, J. Jpn. Petro. Inst., 56(4), 249-252 (2013).
8．Effects of Si/Al Ratio and Pt Loading on Pt/SAPO-11 Catalysts in Hydroconversion of Jatropha Oil, Ning Chen, Shaofeng Gong, Hisakazu Shirai, Toshitaka Watanabe, Eika W. Qian, Applied Catalysis A, Volume 466, 105–115 (2013)
9．Hydrodenitrogenation of porphyrin on Ni-Mo based catalysts, Eika W. Qian, Satoshi Abe, Kurahashi, Tetsuya, Yusaku Kagawa, Hiroyuki Ikeda, Chinese Journal of Catalysis 34 (2013) 152–158
10．Isomerization of n-Alkanes Derived from Jatropha Oil over Bifunctional Catalysts, Shaofeng Gong, Ning Chen, Shin Nakayama, Eika W. Qian, Journal of Molecular Catalysis A: Chemical, 370, 14– 21 (2013).
11．Role of Support in Hydrotreating of Jatropha Oil over Sulfided NiMo Catalysts, Shaofeng Gong, Akira Shinozaki, Eika W. Qian, Industrial & Engineering Chemistry Research, 51(43), 13953-13960 (2012).
12．Hydrotreating of Jatropha Oil over Alumina Based Catalysts, Shaofeng Gong, Akira Shinozaki, Mingliang Shi, Eika W. Qian, Energy & Fuels, Vol.26 (4)，2394-2399 (2012).
13．Preparation of sulfo group bearing mesoporous silica-based solid acid catalysts and its application in direct saccharification, Sen Li, Eika W. Qian, Hosomi Masaaki , Tetsuya Fukunaga, Journal of Chemical Engineering of Japan, Vol. 45, No. 7, 484-492 (2012).
14．Catalytic hydrothermal saccharification of rice straw using mesoporous silica-based solid acid catalysts, Sen Li, Eika W. Qian, Tomohiro Shibata, Masaaki Hosomi, Journal of the Japan Petroleum Institute, Vol. 55, No. 4, 250-260 (2012).
15．Direct saccharification of rice straw using a solid acid catalyst, Sen Li, Eika W. Qian, J. Jpn. Inst. Ener. , Vol 90, No 11, 1065-1071 (2011).
Contact
University Research Administration Center(URAC),
Tokyo University of Agriculture andTechnology
urac[at]ml.tuat.ac.jp
(Please replace [at] with @.)